Structural transformation in magnetite below the Verwey transition
نویسندگان
چکیده
منابع مشابه
Long range charge ordering in magnetite below the Verwey transition.
The crystal structure of Fe(3)O(4) below the 122 K Verwey transition has been refined using high-resolution x-ray and neutron powder diffraction data. The refinements give direct evidence for charge ordering (CO) over four independent octahedral Fe sites, two with a charge of +2.4 and the other two of +2.6. CO schemes consistent with our model do not meet the widely accepted Anderson condition ...
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The historical development and theories explaining the Verwey transition in Magnetite are discussed. An overview of current experimental work is included. Also examined are multiple charge ordering theories and more sophisticated considerations of Jahn-Teller effects which attempt to explain this long-standing problem in strongly-correlated electron systems.
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We have grown epitaxial thin films of magnetite on MgO and Al2O3 substrates with sharp and distinct signatures of the Verwey transition in resistivity and magnetization. We have used Raman scattering to separate the footprint of purely structural changes from the effect of additional charge and orbital order. Raman modes related to the structural phase transition occur first at temperatures abo...
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We present infrared and Raman measurements of magnetite (Fe3O4). This material is known to undergo a metal-insulator and a structural transition (Verwey transition) at TV = 120 K. At temperatures below TV, we observe a
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2011
ISSN: 1098-0121,1550-235X
DOI: 10.1103/physrevb.83.104105